Influence of Particle Size and Chemical Activation on Rice Husk Biochar as Slow Release Fertilizer

Natasha Amelia Rigitha Akhwan, Avido Yuliestyan

Abstract


Nitrogen, Phosphate, and Potassium are important nutritional elements contained in the fertilizers for plants but their presence in the soil could be easily wash out by rain water. Biochar, originated from rice husks with a high absorbance ability, might be able to be used to inhibit the release of those nutrients. This research aims to investigate the influence of biochar size and the HCl chemical activation. Biochar, which has been pyrolyzed, was ground and sieved to obtain powder with the size average equivalent to 0.2735 mm; 0.4485 mm; 0.725mm; and 0.925 mm. The optimized biochar size were opted for later being activated using HCl with a concentration of 3%; 9%; and 15%. The leaching process of fertilizer, aiming to imitate the rain water washing, was performed by pouring water on a daily basis on a sand column with the presence of biochar saturated with colorized fertilizer. The obtained solution were then characterized using Spectrophotometer. The results show that the estimated release time for the case with the absence of biochar is 36 days, in contrast to 55 days for the case with the presence of biochar. 

Keywords


(biochar; spectrophotometer; chemical activator; slow-release fertilizer; leaching)

Full Text:

PDF

References


Ademiluyi, F. T. & David-West, E. O., 2012, Effect of chemical activation on the adsorption of heavy metals using activated carbons from waste materials. International Scholarly Research Network ISRN Chemical Engineering Volume 2012, Article ID 674209, 5 https://doi.org/10.5402/2012/674209

Chen, L., Chen, Q., Rao, P., Yan, L., Shakib, A., & Shen, G., 2018, Formulating and optimizing a novel biochar-based fertilizer for simultaneous slow-release of nitrogen and immobilization of cadmium. Sustainability (Switzerland),Vol.10 No.8 .https://doi.org/10.3390/su10082740

Chen, Ruofei, Liqing, L., Zeng, L., Mingming, L., Chunhao, W., Hailong, L., Weiwu, M., & Shaobin, W., 2017, Preparation and characterization of activated carbons from tobacco stem by chemical activation, Journal of the Air & Waste Management Association, Vol. 67 No.6, April:713-724 https://doi.org/10.1080/10962247.2017.1280560

Chen, R., Zhao, X., Jiao, J., Li, Y., & Wei, M., 2019, Surface-Modified Biochar with Polydentate Binding Sites for the Removal of Cadmium. International Journal Molecular Sciences.Vol.20 No 7, April: 1775. DOI: 10.3390/ijms20071775

El-Hendawy A-NA., 2009, An insight into the KOH activation mechanism through the production of microporous activated carbon for the removal of Pb2+ cations. Appl Surf Sci 2009; 255: 3723–3730.

Fengfeng, M., Baowei, Z., Bin, L., 2015, Adsorption characteristics of ammonium onto biochar derived form corn straw, J. Journal of LanZhou Jiaotong University. 34(1) (2015) 125-132

Glaser, B., Wiedner, K., Seelig, S., Schmidt, H. P., & Gerber, H., 2015, Biochar organic fertilizers from natural resources as substitute for mineral fertilizers. Agronomy for Sustainable Development, Vol. 35 No.2: 667–678. https://doi.org/10.1007/s13593-014-0251-4

Grycová, B., Koutník, I., Pryszcz, A., & Kaloč, M., 2016, Application of pyrolysis process in processing of mixed food wastes. Polish Journal of Chemical Technology, Vol. 18 No.1, 19–23. https://doi.org/10.1515/pjct-2016-0004

Indarto, A. & Hartanto, Y., 2019, Penentuan model adsorpsi metil merah pada karbon aktif berbasis torefaksi arang batubara. Indonesian Journal of Chemical Research. https://doi.org/10.30598//ijcr.2019.7-ind

Li, W., L. Zhang, J. Peng, N. Li, and X. Zhu., 2008, Preparation of high surface area activated carbons from tobacco stems with K2CO3 activation using microwave radiation. Ind. Crops Prod. Vol. 27 No.3:341–7. https://doi.org/10.1016/j.indcrop.2007.11.011

Peiyu, L., Luping, X., Hui, X., Wen, X., 2016, Research of Adsorption on PCBs : Isoterm Modelling and Influencing Factors. MATEC Web of Conferences 67. https://doi.org/10.1051/matecconf/20166706030

Nair V, Vinu R., 2016, Peroxide-assisted microwave activation of pyrolysis char for adsorption of dyes from wastewater. Bioresour Technol, Vol. 216: 511–519.

Sizmur, T., Fresno, T., Akgül, G., Frost, H., Moreno Jiménez, E., 2017, Biochar modification to enhance sorption of inorganics from water, Bioresource Technology,doi: http://dx.doi.org/10.1016/j.biortech.2017.07.082

Tan, X., Liu, Y., Gu, Y., Liu, S., Zeng, G., Cai, X., Hu, X., Wang, H., Liu, S., and Jiang L., 2016, Biochar Pyrolyzed from MgAl-layered Double Hydroxides Pre-coated Ramie Biomass (Boehmeria niveria(L/) Gaud): Characterization and Application for Crystal Violet Removal. Journal of Environment Management, Vol.184 : 85-93.

Zhong, X., Wang, M., and Jiang, E., 2018, Preparation of an environment-friendly biochar fertilizer. IOP Conference Series: Materials Science and Engineering, Vol. 301 No.1 .https://doi.org/10.1088/1757899X/301/1/012157




DOI: https://doi.org/10.31315/e.v17i2.3730

Refbacks

  • There are currently no refbacks.

Article Metrics

Metrics Loading ...

Metrics powered by PLOS ALM


Eksergi p-ISSN  1410-394X, e-ISSN 2460-8203,  is published by "Prodi Teknik Kimia UPN Veteran Yogyakarta".

Contact  Jl. SWK 104 (Lingkar Utara) Condong catur Sleman Yogyakarta

 

 Creative Commons License

Eksergi by http://jurnal.upnyk.ac.id/index.php/eksergi/index/ is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.

 

 

Lihat Statistik Jurnal Kami

slot gacor slot gacor hari ini slot gacor 2025 demo slot pg slot gacor slot gacor