Pengaruh Pelarut Terhadap Persentase Kopolimerisasi Cangkok Asam Akrilat pada Khitin dengan Metode Iradiasi
Abstract
The effect of solvent on the percentage of graft copolymerization of acrylic acid onto chitin by irradiation method has been carried out. The research aims to find out the optimum solvent composition to the increased swelling properties of chitin so that acrylic acid could carry in the active site of chitin. In this experiment, the trapped radical and peroxide graft copolymerization radiation method were employed. The influence of solvent compositions e.g., water-methanol, water-acetic acid, and methanol-acetic acid, and the grafting method that affected the degree of grafting have been studied. The result showed that the percentage of grafted chitin by pre-irradiation peroxide method is higher than the trapped radical method. The methanol-acetic acid in the composition of 7/3 was the best solvent for grafting of chitin, with the percentage of grafting was found 47.2 %.
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Brandrup J, Immergut EH, Grulke EA, Abe A, Bloch DR. Polymer handbook Vol. 7. Wiley New York etc, 1989.
Bhattacharya A. Radiation and industrial polymers. Prog. Polym. Sci. 2000; 25 (3): 371-401.
Casimiro M, Botelho M, Leal J, Gil M. Study on chemical, UV and gamma radiation-induced grafting of 2-hydroxyethyl methacrylate onto chitosan. Radiat. Phys. Chem. 2005; 72 (6): 731-735.
Ciechanska D, Chmielewski A, Hien N, Machi S, Nho YC, Kume T, Sabharwal S, Tamada M, Yoshii F. Radiation processing of polysaccharides. In IAEA-TECDOC-1422, International Atomic Energy Agency Viena, Austria. 2004: 29-38.
Cui Z, Coletta C, Rebois R, Baiz S, Gervais M, Goubard, F., Aubert, P.-H., Dazzi, A., Remita, S. Radiation-induced reduction–polymerization route for the synthesis of PEDOT conducting polymers. Radiat. Phys. Chem. 2016; 119: 157-166.
Miretzky P, Cirelli AF. Hg (II) removal from water by chitosan and chitosan derivatives: A review. J. Hazard. Mater 2009; 167 (1-3): 10-23.
Ngah WW, Fatinathan S. Pb (II) biosorption using chitosan and chitosan derivatives beads: Equilibrium, ion exchange and mechanism studies. Journal of Environmental Sciences 2010; 22 (3): 338-346.
Rekso GT. Chemical and physical properties of cassava starch–CM-chitosan–acrylic acid gel copolymerization by gamma irradiation. Indonesian Journal of Chemistry 2014; 14 (1): 37-42.
Rekso GT. Kopolimerisasi cangkok dan karakterisasi lembaran kitosan teriradiasi. Jurnal Kimia Dan Kemasan 2014; 36 (1).
Ting TM, Nasef MM, Aw EL. Kinertics of radiation grafting of glycidyl methacrylate and vinylbenzyl chloride onto polymer fibers. Journal of Engineering Science and Technology 2019; 14 (2): 646-658.
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