Intensifikasi Proses dalam Sistem Reaksi dan Pemisahan Dinamik

Yogi Wibisono Budhi

Abstract


Process Intensification (PI) presents a set of often substantially innovative and creative methods in process equipment design and operation method, which could bring considerable benefits in term of process performance. The process intensification in principle is a paradigm shift of thinking when compared to traditional processes. Transient reactors and separations are receiving increased attention due to its capability to influence the temperature and concentration profiles inside the fixed bed as well as main product recovery, leading to the possibility for improvement of conversion, selectivity, and recovery. The application of the transient fixed bed and membrane reactors is also gaining broad interest as an efficient method for energy saving, lower light-off temperature, and higher recovery. This technology may be considered as an alternative to various catalytic reactions in which heat storage and catalytic coverage can be manipulated for the process improvement. In this paper, possible operations and methods of fixed bed catalytic reactor and membrane operation are presented. Examples are given here for modulation of feed gas in catalytic converter and membrane, and application of reverse flow reactor. Overall, the process intensification opens a new way for improvement of process performance when proper design and operation can be developed.


Keywords


converter; dynamic; membrane; reactor; reverse flow

Full Text:

PDF (Indonesian)

References


Budhi YW, Devianto H, Ignacia L, Mikhael HA. Process intensification of hydrogen production from ethanol using microreactor. The 3rd International Conference in Electrical Vehicular Technology (ICEVT), Solo, Indonesia; 2015

Budhi YW, Devianto H, Mahardhika F, Ignacia L, Mikhael HA. Fluid dynamics and kinetic simulation for steam reforming of ethanol using a microchannel reactor. International Conference on Electrical Engineering and Computer Science (ICEECS), Bali, Indonesia; 2014

Budhi YW, Gideon PE, Kristianto J, Susanto H. Studi eksperimental konversi tar menggunakan reverse flow reaktor. Pros. Seminar Teknik Kimia “Soehadi Reksowardojo”, Bandung, Indonesia; 2008. (ISSN: 0854-7769).

Budhi YW, Hoebink JHBJ, Schouten JC. Reverse flow operation with reactor side feeding: Analysis, modeling, and simulation. Industrial and Engineering Chemistry Research 2004b; 43: 6955-6963.

Budhi YW, Jaree A, Hoebink JHBJ, Schouten JC. Simulation of reverse flow operation for manipulation of catalyst surface coverage in the selective oxidation of ammonia. Chemical Engineering Science 2004a; 59: 5365-5377.

Budhi YW, Noezar I, Aldiansyah F, Kemala PV, Padama AAB, Kasai H. Forced unsteady state operation to improve H2 permeability through Pd–Ag membrane during start-up. International Journal of Hydrogen Energy 2011; 36 (23): 15372-15381.

Budhi YW, Putri AK, Nashira A, Forced unsteady state operation of a catalytic converter during cold xtart-up for oxidizing CO over Pt/γ-Al2O3 catalyst. Asia Pacific Conference on Chemical Engineering, Sapporo, Japan; 2019

Budhi YW, Rionaldo YW, Padama AAB, Kasai H, Noezar I. Forced unsteady state operation for hydrogen separation through Pd–Ag membrane after start-up. International Journal of Hydrogen Energy 2015; 40 (32): 10081-10089.

Budhi YW, Suganda W, Irawan HK, Restiawaty E, Miyamoto M, Uemiya S, Nishiyama N, van Sint Annaland M. Hydrogen separation from mixed gas (H2, N2) using Pd/Al2O3 membrane under forced unsteady state operations. International Journal of Hydrogen Energy 2020; 45 (16): 9821-9835, 2020

Ebrahimi H, Rahman M. Hydrogen production in membrane microreactor using chemical looping combustion: A dynamic simulation study. International Journal of Hydrogen Energy 2017; 42 (1): 265-278.

Effendy M, Budhi YW, Susanto H. Pemodelan dan simulasi reverse flow reactor untuk mengkonversikan tar menjadi CO dan H2. Pros. Seminar Teknik Kimia “Soehadi Reksowardojo”, Bandung, Indonesia; 2008. (ISSN: 0854-7769).

Harmsen, J. Process Intensification in The Petrochemicals Industry: Drivers and Hurdles for Commercial Implementation. Chemical Engineering and Processing: Process Intensification 2009; 49(1): 70-73.

Hayes RE. Catalytic solutions for fugitive methane emissions in oil and gas sector. Chemical Engineering Science 2004; 19: 4073-4080.

Litto R, Hayes RE, Liu B. Capturing fugitive methane emissions from natural gas compressor buildings. Journal of Environmental Management 2006; 84(3): 347-361.

Marín P, Ordóñez S, Díez FV. Performance of reverse flow monolithic reactor for water–gas shift reaction. Catalysis Today 2009; 147: S185-S190.

Matros YuSh, Buminovich GH. Reverse flow operation in fixed bed catalytic reactors. Catalyst Review-Science and Engineering 1996; 38: 1-96.

Ramshaw C. Higee distillations – an example of process intensification. Chemical Engineering 1983; London, 389: 13–14.

Salomons S, Hayes RE, Poirier M, Sapoundjiev H. Modelling a reverse flow reactor for the catalytic combustion of fugitive methane emissions. Computers and Chemical Engineering 2004; 28: 1599–1610.

Stankiewicz A, Drinkenburg AAH. Process intensification: history, philosophy, principles. In: Stankiewicz A, Moulijn JA, editors. Re-engineering the chemical processing plant: process intensification. New York/USA: Marcel Dekker, 2004

Stankiewicz A, Moulijn JA. Re-engineering the chemical processing plant: process intensification. CRC Press. 2003: ISBN 9780824743024.

Zhang X, Xiong G, Yang W. A modified electroless plating technique for thin dense palladium composite membranes with enhanced stability. Journal of Membrane Science 2008; 314: 226-237.

Zheng T, Zhou W, Yu W, Ke Y, Liu Y, Liu R, Hui KS. Methanol steam reforming performance optimisation of cylindrical microreactor for hydrogen production utilising error backpropagation and genetic algorithm. Chemical Engineering Journal 2019; 357: 641-654.


Refbacks

  • There are currently no refbacks.