Evaluation of Chicken Bone-Derived CaO Catalyst for biodiesel production from waste cooking oil

Ilham Mufandi, Muhammad Nur Kholis, Arief Rahmawan, Ratchaphon Suntivarakorn, Dhaifullah Nafis Nugraha, Raka Wyztyo Alana P

Sari


This research explores the use of waste cooking oil (WCO) into biodiesel and adding a calcium oxide (CaO) catalyst derived from chicken bone waste. The synthesized CaO catalyst was characterized using FTIR and SEM to determine its structural and chemical properties. Biodiesel production experiments were carried out at a temperature of 60°C with an oil-to-methanol ratio of 9:1 and a CaO catalyst load of 5% concentration. The biodiesel produced is characterized by its main quality parameters, including flash point, density, acid number, viscosity, and heating value. The research results show that the CaO catalyst contains various organic compounds, including haloalkanes, 1,2-disubstituted functional groups, primary alcohols, aromatic compounds, and alcohols. In addition, the CaO catalyst contains mineral compositions such as calcium, carbon, oxygen, sodium, magnesium, and phosphorus. Biodiesel yield increases significantly with increasing catalyst loading, reaching a maximum of 92.70% at 15% catalyst loading. This research shows the effectiveness of the CaO catalyst derived from chicken bone waste for environmentally friendly biodiesel production using microwave technology.

Kata Kunci


Biodiesel, CaO Catalyst, Chicken Bone Waste, Waste Cooking Oil (WCO)

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Referensi


Adhikesavan C., Ganesh D., & Charles Augustin, V. (2022). Effect of quality of waste cooking oil on the properties of biodiesel, engine performance and emissions. Cleaner Chemical Engineering, 4, 100070. https://doi.org/10.1016/j.clce.2022.100070

Aini, N., Mufandi, I., Jamilatun, S., & Rahayu, A. (2023). Exploring Cacao Husk Waste – Surface Modification, Characterization, and its Potential for Removing Phosphate and Nitrate Ions. Journal of Ecological Engineering, 24(12), 282–292. https://doi.org/10.12911/22998993/174003

Arul, E., Raja, K., Krishnan, S., Sivaji, K., & Das, S. J. (2018). Bio-Directed Synthesis of Calcium Oxide (CaO) Nanoparticles Extracted from Limestone Using Honey. Journal of Nanoscience and Nanotechnology, 18(8), 5790–5793. https://doi.org/10.1166/jnn.2018.15386

Azzahro, U. L., & Broto, W. (2021). Pemanfaatan Limbah Cangkang Kerang Dara Sebagai Katalis CaO Pada Pembuatan Biodiesel Minyak Goreng Bekas. Jurnal Sosial Dan Teknologi (SOSTECH), 1(6). https://greenvest.co.id/

Chen, C., Jia, W., Liu, S., & Cao, Y. (2018). The enhancement of CuO modified V2O5-WO3/TiO2 based SCR catalyst for Hg° oxidation in simulated flue gas. Applied Surface Science, 436, 1022–1029. https://doi.org/https://doi.org/10.1016/j.apsusc.2017.12.123

Chen, L., Yang, S., Nan, Z., Li, Y., Ma, J., Ding, J., Lv, Y., & Yang, J. (2023). Detection of dextran, maltodextrin and soluble starch in the adulterated Lycium barbarum polysaccharides (LBPs) using Fourier-transform infrared spectroscopy (FTIR) and machine learning models. Heliyon, 9(6). https://doi.org/10.1016/j.heliyon.2023.e17115

Ferriansyah, R. M., & Hadiantoro, S. (2021). Penggunaan Serbuk Tulang Ayam Sebagai Adsorben Dengan Aktivator HCL Dan NaOH Untuk Mengurangi Ion Logam Kromium. Distilat Jurnal Teknologi Separasi, 2021(2), 494–499. http://distilat.polinema.ac.id

González-Santamaría, D. E., Justel, A., Fernández, R., Ruiz, A. I., Stavropoulou, A., Rodríguez-Blanco, J. D., & Cuevas, J. (2021). SEM-EDX study of bentonite alteration under the influence of cement alkaline solutions. Applied Clay Science, 212. https://doi.org/10.1016/j.clay.2021.106223

Hsiao, M. C., Kuo, J. Y., Hsieh, S. A., Hsieh, P. H., & Hou, S. S. (2020). Optimized conversion of waste cooking oil to biodiesel using modified calcium oxide as catalyst via a microwave heating system. Fuel, 266(July 2019), 117114. https://doi.org/10.1016/j.fuel.2020.117114

Iqbal, M., Ghifari, A., & Samik, S. (2023). Review: Pembuatan Biodiesel Dengan Metode Transesterifikasi Menggunakan Katalis Berbahan Limbah Tulang. In UNESA Journal of Chemistry (Vol. 12, Issue 1).

Jamilatun, S., Aktawan, A., Budiman, A., & Mufandi, I. (2022). Thermogravimetric analysis kinetic study of Spirulina platensis residue pyrolysis. IOP Conference Series: Earth and Environmental Science, 963(1). https://doi.org/10.1088/1755-1315/963/1/012010

Kementerian Energi dan Sumber Daya Mineral. (2022). Statistik Minyak dan Gas Bumi 2022.

Khan, H. M., Iqbal, T., Ali, C. H., Yasin, S., & Jamil, F. (2020). Waste quail beaks as renewable source for synthesizing novel catalysts for biodiesel production. Renewable Energy, 154, 1035–1043. https://doi.org/10.1016/j.renene.2020.03.079

Mohamed, M. A., Jaafar, J., Ismail, A. F., Othman, M. H. D., & Rahman, M. A. (2017). Chapter 1 - Fourier Transform Infrared (FTIR) Spectroscopy (N. Hilal, A. F. Ismail, T. Matsuura, & D. B. T.-M. C. Oatley-Radcliffe (eds.); pp. 3–29). Elsevier. https://doi.org/https://doi.org/10.1016/B978-0-444-63776-5.00001-2

Nur Ajizah, D., Nur Fitriana, I., Setiawati, A., Khotimah, K., Listianingrum, D., & Kusumawardani, R. (2022). Pemanfaatan Tulang Ayam Sebagai Adsorben Methylene Blue. Jurnal Zarah, 10(2), 73–79.

Nur Shuhaila Haryani Haris, Nafisah Mansor, M. A. K. (2022). Supramolecular Assemblies Of 1 , 2-Disubstituted Cyclohexane Amide Ligands And Their Coordination Polymer : Synthesis , Characterisation , And Crystal Structure. 26(1), 70–83.

Oko, S., & Feri, M. (2019). Pengembangan Katalis CaO dari Cangkang Telur Ayam dengan Impregnasi KOH Dan Aplikasinya Terhadap Pembuatan Biodiesel dari Minyak Jarak. Jurnal Teknologi, 11(2). https://doi.org/10.24853/jurtek.11.2.103-110

Sharma, A., Kodgire, P., & Kachhwaha, S. S. (2019). Biodiesel production from waste cotton-seed cooking oil using microwave-assisted transesterification: Optimization and kinetic modeling. Renewable and Sustainable Energy Reviews, 116(November 2018), 109394. https://doi.org/10.1016/j.rser.2019.109394

Sharma, V., & Bhardwaj, A. (2019). Scanning electron microscopy (SEM) in food quality evaluation. In Evaluation Technologies for Food Quality (pp. 743–761). Elsevier. https://doi.org/10.1016/B978-0-12-814217-2.00029-9

Simpen, I. N., Negara, I. M. S., & Ratnayani, O. (2021). Karakteristik Fisiko-Kimia Katalis Heterogen CaO-Base Dan Pemanfaatannya Untuk Konversi Minyak Goreng Bekas Secara Sinambung Menjadi Biodiesel. Jurnal Kimia, 2(15), 188. https://doi.org/10.24843/jchem.2021.v15.i02.p09

Tan, Y. H., Abdullah, M. O., Nolasco-Hipolito, C., & Taufiq-Yap, Y. H. (2015). Waste ostrich- and chicken-eggshells as heterogeneous base catalyst for biodiesel production from used cooking oil: Catalyst characterization and biodiesel yield performance. Applied Energy, 160, 58–70. https://doi.org/10.1016/j.apenergy.2015.09.023

Welela Meka Kedir, et al. (2023). Optimization and characterization of biodiesel from waste cooking oil using modified CaO catalyst derived from snail shell. Heliyon, 9(5). https://doi.org/10.1016/j.heliyon.2023.e16475

Widiarti, N., & Kusumastuti, E. (2015). Modifikasi Katalis CaO Dengan SrO Pada Reaksi Transesterifikasi Minyak Jelantah Menjadi Biodiesel Menggunakan. Jurnal MIPA, 38(1), 49–56. http://journal.unnes.ac.id/nju/index.php/JM




DOI: https://doi.org/10.31315/e.v21i2.12254

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