Pengaruh Gliserol sebagai Plasticizer terhadap Karakterisasi Edible Film dari Kappa Karaginan
DOI:
https://doi.org/10.31315/e.v21i3.12451Keywords:
edible film, kappa karaginan, gliserol, kemasanAbstract
Perkembangan industri pengemasan makanan di era mendatang akan beralih ke bahan alami dan ramah lingkungan yang bisa diproduksi dari biopolimer seperti pati dan hidrokoloid lainnya untuk mengurangi paparan polusi dari polimer sintetis. Kappa karaginan memiliki sifat yang rapuh, sehingga dibutuhkan plasticizer untuk menghasilkan edible film yang lebih elastis. Jenis plasticizer yang digunakan adalah gliserol. Tujuan dari penelitian ini adalah untuk mengetahui pengaruh konsentrasi gliserol terhadap karakterisasi edible film dari kappa karaginan. Kappa karaginan dengan konsentrasi 1% (b/v) dilarutkan dengan akuades kemudian ditambahkan gliserol dengan variasi konsentrasi 0,5; 1; 1,5, dan 2% (b/v). Edible film kemudian di karakterisasi berdasarkan sifat mekanik, gugus fungsional, ketebalan, kadar air, kuat tarik, elongasi, warna dan opacity. Hasil analisa menunjukkan bahwa penambahan gliserol sebesar 1% dapat meningkatkan sifat mekaniknya, dan film mempunyai 0,146 mm, kadar air 17,90%, kuat tarik dan elongasi 2,53 MPa dan 14,09% dan sifat optik warna dan opacity masing-masing sebesar 96,96% dan 1,32.
References
Arik Kibar, E. A., & Us, F. (2017). Starch–Cellulose Ether Films: Microstructure and Water Resistance. Journal of Food Process Engineering, 40(2). https://doi.org/10.1111/jfpe.12382
Asfaw, W. A., Tafa, K. D., & Satheesh, N. (2023). Optimization of citron peel pectin and glycerol concentration in the production of edible film using response surface methodology. Heliyon, 9(3), e13724. https://doi.org/10.1016/j.heliyon.2023.e13724
Chen, L., Dai, T., Chen, Y., Han, Y., Copyright, fnut, Cheng, C., Chen, S., Su, J., Zhu, M., Zhou, M., & Chen, T. (2022). OPEN ACCESS EDITED BY Recent advances in carrageenan-based films for food packaging applications.
Dick, M., Costa, T. M. H., Gomaa, A., Subirade, M., Rios, A. de O., & Flôres, S. H. (2015). Edible film production from chia seed mucilage: Effect of glycerol concentration on its physicochemical and mechanical properties. Carbohydrate Polymers, 130, 198–205. https://doi.org/10.1016/j.carbpol.2015.05.040
Dong, Y., Li, Y., Ma, Z., Rao, Z., Zheng, X., Tang, K., & Liu, J. (2023). Effect of polyol plasticizers on properties and microstructure of soluble soybean polysaccharide edible films. Food Packaging and Shelf Life, 35, 101023. https://doi.org/10.1016/j.fpsl.2022.101023
Fadilah, Susanti, A. D., Distantina, S., Purnamasari, D. P., & Ahmad, J. F. (2020). Mechanical properties of films from carboxy methyl glucomannan and carrageenan with glycerol as plasticizer. AIP Conference Proceedings, 2217. https://doi.org/10.1063/5.0000842
Fahrullah, F., Radiati, L. E., Purwadi, P., & Rosyidi, D. (2020a). The Effect of Different Plasticizers on the Characteristics of Whey Composite Edible Film. Jurnal Ilmu Dan Teknologi Hasil Ternak, 15(1), 31–37. https://doi.org/10.21776/ub.jitek.2020.015.01.4
Fahrullah, F., Radiati, L. E., Purwadi, P., & Rosyidi, D. (2020b). The Effect of Different Plasticizers on the Characteristics of Whey Composite Edible Film. Jurnal Ilmu Dan Teknologi Hasil Ternak, 15(1), 31–37. https://doi.org/10.21776/ub.jitek.2020.015.01.4
Farhan, A., & Hani, N. M. (2017). Characterization of edible packaging films based on semi-refined kappa-carrageenan plasticized with glycerol and sorbitol. Food Hydrocolloids, 64, 48–58. https://doi.org/10.1016/j.foodhyd.2016.10.034
Fatnasari, A., Nocianitri, K. A., & Suparthana, I. P. (2018). The Effect of Glycerol Concentration on The Characteristic Edible Film Sweet Potato Starch (Ipomoea batatas L.). Scientific Journal of Food Technology), 5(1), 27–35.
Guidara, M., Yaich, H., Benelhadj, S., Adjouman, Y. D., Richel, A., Blecker, C., Sindic, M., Boufi, S., Attia, H., & Garna, H. (2020). Smart ulvan films responsive to stimuli of plasticizer and extraction condition in physico-chemical, optical, barrier and mechanical properties. International Journal of Biological Macromolecules, 150, 714–726. https://doi.org/10.1016/j.ijbiomac.2020.02.111
Horwitz, W. (2006). Official methods of analysis of AOAC International. AOAC International.
Huang, M., Yu, J., & Ma, X. (2005). Ethanolamine as a novel plasticiser for thermoplastic starch. Polymer Degradation and Stability, 90(3), 501–507. https://doi.org/10.1016/j.polymdegradstab.2005.04.005
Irawan, S. (2010). Pengaruh Gliserol terhadap Sifat Fisik/Mekanik dan Barrier Edible Film dari Kitosan. Jurnal Kimia Dan Kemasan, 32(1), 6. https://doi.org/10.24817/jkk.v32i1.2735
Karbowiak, T., Hervet, H., Léger, L., Champion, D., Debeaufort, F., & Voilley, A. (2006a). Effect of Plasticizers (Water and Glycerol) on the Diffusion of a Small Molecule in Iota-Carrageenan Biopolymer Films for Edible Coating Application. Biomacromolecules, 7(6), 2011–2019. https://doi.org/10.1021/bm060179r
Karbowiak, T., Hervet, H., Léger, L., Champion, D., Debeaufort, F., & Voilley, A. (2006b). Effect of Plasticizers (Water and Glycerol) on the Diffusion of a Small Molecule in Iota-Carrageenan Biopolymer Films for Edible Coating Application. Biomacromolecules, 7(6), 2011–2019. https://doi.org/10.1021/bm060179r
Martiny, T. R., Raghavan, V., de Moraes, C. C., da Rosa, G. S., & Dotto, G. L. (2020). Bio-based active packaging: Carrageenan film with olive leaf extract for lamb meat preservation. Foods, 9(12). https://doi.org/10.3390/foods9121759
Maruddin, F., Malaka, R., Baba, S., Amqam, H., Taufik, M., & Sabil, S. (2020). Brightness, elongation and thickness of edible film with caseinate sodium using a type of plasticizer. IOP Conference Series: Earth and Environmental Science, 492(1), 012043. https://doi.org/10.1088/1755-1315/492/1/012043
Medeiros Silva, V. D., Coutinho Macedo, M. C., Rodrigues, C. G., Neris dos Santos, A., de Freitas e Loyola, A. C., & Fante, C. A. (2020). Biodegradable edible films of ripe banana peel and starch enriched with extract of Eriobotrya japonica leaves. Food Bioscience, 38. https://doi.org/10.1016/j.fbio.2020.100750
Necas, J., & Bartosikova, L. (2013). Carrageenan: a review. In Veterinarni Medicina (Vol. 58, Issue 4).
Prasetyaningrum, A., Utomo, D. P., Raemas, A. F. A., Kusworo, T. D., Jos, B., & Djaeni, M. (2021). Alginate/κ-Carrageenan-Based Edible Films Incorporated with Clove Essential Oil: Physico-Chemical
Characterization and Antioxidant-Antimicrobial Activity. Polymers, 13(3), 354. https://doi.org/10.3390/polym13030354
Rahmawati, M., Arief, M., & Satyantini, W. H. (2019). The Effect of Sorbitol Addition on the Characteristic of Carrageenan Edible Film. IOP Conference Series: Earth and Environmental Science, 236, 012129. https://doi.org/10.1088/1755-1315/236/1/012129
Rajeswari, A., Christy, E. J. S., Swathi, E., & Pius, A. (2020). Fabrication of improved cellulose acetate-based biodegradable films for food packaging applications. Environmental Chemistry and Ecotoxicology, 2, 107–114. https://doi.org/10.1016/j.enceco.2020.07.003
Rane, L. R., Savadekar, N. R., Kadam, P. G., & Mhaske, S. T. (2014). Preparation and Characterization of K-Carrageenan/Nanosilica Biocomposite Film. Journal of Materials, 2014, 1–8. https://doi.org/10.1155/2014/736271
Summo, C., & De Angelis, D. (2022). The Importance of Edible Films and Coatings for Sustainable Food Development. https://doi.org/10.3390/foods
Tharanathan, R. N. (2003). Biodegradable films and composite coatings: Past, present and future. In Trends in Food Science and Technology (Vol. 14, Issue 3, pp. 71–78). Elsevier Ltd. https://doi.org/10.1016/S0924-2244(02)00280-7
Venugopal, V. (2016). Marine Polysaccharides. CRC Press. https://doi.org/10.1201/b10516
Vieira, M. G. A., da Silva, M. A., dos Santos, L. O., & Beppu, M. M. (2011). Natural-based plasticizers and biopolymer films: A review. European Polymer Journal, 47(3), 254–263. https://doi.org/10.1016/j.eurpolymj.2010.12.011
Warren, F. J., Gidley, M. J., & Flanagan, B. M. (2016). Infrared spectroscopy as a tool to characterise starch ordered structure—a joint FTIR–ATR, NMR, XRD and DSC study. Carbohydrate Polymers, 139, 35–42. https://doi.org/10.1016/j.carbpol.2015.11.066
Wicherts, J. M. (2016). Peer Review Quality and Transparency of the Peer-Review Process in Open Access and Subscription Journals. PLOS ONE, 11(1), e0147913. https://doi.org/10.1371/journal.pone.0147913
Xiao, M., Luo, L., Tang, B., Qin, J., Wu, K., & Jiang, F. (2022). Physical, structural, and water barrier properties of emulsified blend film based on konjac glucomannan/agar/gum Arabic incorporating virgin coconut oil. LWT, 154, 112683. https://doi.org/10.1016/j.lwt.2021.112683
Downloads
Published
How to Cite
Issue
Section
License
Authors who publish with this journal agree to the following terms:
Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution-ShareAlike 4.0 International License(CC BY SA 4.0) that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.
Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgement of its initial publication in this journal.
Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work (See The Effect of Open Access).
Eksergi allows authors retain the copyright and full publishing rights without restrictions.